Just realized this was covered in the video module. Page 2
Just realized this was covered in the video module. Page 3If you know the percent composition and the molar mass of a compound, here's how you can determine its molecular formula. A compound's molar mass tells you what the exact mass of 1 mole of that compound is. In your case, you know that ascorbic acid has a molar mass of 176.1 g/mol. This means that 1 mole of ascorbic acid has a total mass of 176.1 g. Let's assume that you have a 176.1-g sample of ascorbic acid. According to ascorbic acid's percent composition, every 100 g of acid will contain 40.92 g carbon, 4.58 g hydrogen, and 54.50 g oxygen. This means that your 176.1-g sample will contain #176.1cancel("g") * "40.92 g C"/(100cancel("g")) = "72.06 g C"# #176.1cancel("g") * "4.58 g H"/(100cancel("g")) = "8.065 g H"# #176.1cancel("g") * "54.50 g"/(100cancel("g")) = "95.97 g O"# To get the number of moles each element contributes to 1 mole of ascorbic acid, simply divide these numbers by each element's molar mass #"For C": (72.06cancel("g"))/(12.0cancel("g")/"mol") = 6.005 ~= 6# #"For H": (8.065cancel("g"))/(1.01cancel("g")/"mol") = 7.985 ~= 8# #"For O": (95.97cancel("g"))/(16.0cancel("g")/"mol") = 5.998 ~= 6# Therefore, the molecular formula of ascorbic acid is #C_6H_8O_6# One mole of ascorbic acid contains 6 moles of carbon, 8 moles of hydrogen, and 6 moles of oxygen. Yes,the molecular and empirical formulae of one substance can be same. It is generally known relation: Molecular formula = n[empirical formula] Where, n=molecular mass/empirical formula mass For all the substances for which ratio between molecular mass and empirical formula mass is unity(i.e.)n=1 , Molecular formula = empirical formula. This can be observed in H2O,NH3,CO2,C12H22O11 and many other substances. |